Basic Concepts of Thermodynamics: Thermodynamics and
Energy-System-Energy of A system-Properties of A system- state of a system-equilibrium-thermodynamics
processes and cycles-pressure and temperature-units and dimensions.
Properties of Pure substances: pure substance-phases
of pure substance-phase change processes-property diagrams-property tables-the
ideal gas equation of state-compressibility factor-other equations of state.
The First Law of Thermodynamics: Introduction-heat
transfer-work-specific heats, Internal Energy and Enthalpy-thermodynamic
analysis of closed systems-thermodynamics analysis of control-volumes-the
steady-flow processes-the unsteady-flow processes.
The 2nd Law of Thermodynamics:
Introduction-Thermal energy reservoir-heat engines, refrigerators and heat
pumps- the reversible and irreversible processes-the carnot principles-the
thermodynamics temperature scale-entropy-the Clausius Inequality-Tds relations-entropy
change of pure substances-the third law of thermodynamics-entropy from
microscopic viewpoint-thermodynamics of flow processes.
Power Cycles: Gas cycles (analysis of power cycles-carnot
cycle-reciprocating engines-Otto cycle-Diesel Cycle) - Vapor Cycles (Carnot
vapor cycle-Rankine cycle-Steam power plant-Cogeneration)
Thermodyanimc Property relations: Property relations
for homogeneous phases-residual properties-two-phase systems- thermodynamics
diagrams-tables of thermodynaimcs properties-generalised property relations
for gases.
Solution Thermodynamics: Fundamental property relation-chemical
potential-partial properties-ideal gas mixtures-fugacity coefficient-the
ideal solution-excess properties-activity coefficient.
Phase Equilibrium: The nature of equilibrium-the phase
rule-VLE (Qualitative behaviour-VLE at low to moderate pressure-gamma/Phi
Formulation-Dewpoint and Bubble Point)- Calculations (Flash calculations-
VLE at high pressure- K-value Method - Equations of State- Activity Coefficient-
Phase diagrams-thermodynamics properties for solution- liquid phase properties
from VLE - solubility-Fluid properties from equation of states- LLE, SLE
and SVE).
Chemical Equilibrium: Criterion for chemical equilibrium-the
standard Gibbs energy change and equilibrium constant-effect of temperatures
on equilibrium constant- evaluation of equilibrium constant to composition-Equilibrium
conversions for single reactions-phase rule for reacting systems-multi
reaction equilibria.
References
Daubert, Thomas E., Chemical Engineering Thermodynamics,
McGraw-Hill, 1985. (The bahasa version is available at the library, translated
by Prof.Mashitah Hassan, 1990).